a) Chất rắn không tan là Cu

=> m Cu = 19,2(gam)

n Mg = a(mol) ; n Fe = b(mol)

=> 24a + 56b = 32,8 -19,2 = 13,6(1)

$Mg + H_2SO_4 \to MgSO_4 + H_2$
$Fe + H_2SO_4 \to FeSO_4 + H_2$
n H2 = a + b = 6,72/22,4 = 0,3(2)

Từ (1)(2) suy ra a = 0,1 ; b = 0,2

%m Cu = 19,2/32,8  .100% = 58,54%
%m Mg = 0,1.24/32,8   .100% = 7,32%
%m Fe = 100% -58,54% -7,32% = 34,14%

b)

m dd A = 32,8 + 200 - 0,3.2 = 232,2(gam)

n MgSO4 = a = 0,1(mol)

n FeSO4 = b = 0,2(mol)

C% MgSO4 = 0,1.120/232,2   .100% = 5,17%
C% FeSO4 = 0,2.152/232,2   .100% = 13,09%

a,\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\);\(n_{hhNO;NO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: 3Zn + 8HNO₃ → 3Zn(NO₃)₂ + 2NO + 4H₂O

Mol:      x                                                2/3x

PTHH: Zn + 4HNO₃ → Zn(NO₃)₂ + 2NO₂ + 2H₂O

Mol:      y                                            2y

Ta có: \(\left\{{}\begin{matrix}x+y=0,4\\\dfrac{2}{3}x+2y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\\y=0,1\end{matrix}\right.\)

PTHH: 3Zn + 8HNO₃ → 3Zn(NO₃)₂ + 2NO + 4H₂O

Mol:      0,3      0,8               0,3             0,2

PTHH: Zn + 4HNO₃ → Zn(NO₃)₂ + 2NO₂ + 2H₂O

Mol:     0,1      0,4                 0,1        0,2

\(m_{HNO_3}=\left(0,8+0,4\right).63=75,6\left(g\right)\)

\(\Rightarrow m_{ddHNO_3}=\dfrac{75,6.100}{10}=756\left(g\right)\)

b,m_{dd sau pứ} = 26+756-0,2.30-0,2.46 = 766,8 (g)

\(C\%_{ddZn\left(NO_3\right)_2}=\dfrac{\left(0,3+0,1\right).189.100\%}{766,8}=9,86\%\)

Đáp án A

n_Zn=0,66 mol => n_Zn(NO3)2=0,66 mol => m_NH4NO3=129,54-0,66.189=4,8 gam => n_NH4NO3=0,06 mol

G/s: NO: x mol; N₂O=y mol

x+y=4,032/22,4=0,18

3x+2y.4+8.0,06=0,66.2 (BT e)

=> x=0,12; y=0,06

BTNT N: n_HNO3=2n_Zn(NO3)2+n_NO+2n_N2O+2n_NH4NO3=2.0,66+0,12+2.0,06+2.0,06=1,68 mol

V=m_dd/d=[m_HNO3.100/C]/d=(1,68.63.100/10)/1,26=840 ml

n_H2 = \(\dfrac{4,48}{22,4}\) = 0,2 (mol)

Zn + 2HCl ----> ZnCl₂ + H₂ (1)

ZnO + 2HCl ----> ZnCl₂ + H₂O (2)

n_Zn = n_{ZnCl2 (1)} = n_H2 = 0,2 (mol)

=> m_Zn = 0.2 x 65 = 13 (g)

=> m_ZnO = 21,1 - 13 = 8,1 (g)

=> n_ZnO = 8,1/81 = 0.1 (mol)

n_{ZnCl2 (2)} = n_ZnO = 0.1 (mol)

C%_ZnCl2 = \(\dfrac{152\left(0,2+0,1\right)}{21,1+200}\times100\%=20.62\%\)

\(n_{HNO_3}=1.2\left(mol\right)\)

\(n_{NO}=a\left(mol\right)\)

\(n_{NO_2}=b\left(mol\right)\)

\(n_{N_2}=c\left(mol\right)\)

\(\Rightarrow a+b+c=\dfrac{5.6}{22.4}=0.25\left(1\right)\)

Bảo toàn e : 

\(3\cdot0.2+1\cdot0.3=3a+b+10c\left(2\right)\)

\(n_{H^+}=4n_{NO}+2n_{NO_2}+12n_{N_2}\)

\(\Rightarrow4a+2b+12c=1.2\left(3\right)\)

\(\left(1\right),\left(2\right),\left(3\right):a=b=0.1,c=0.05\)

\(\%V_{NO_2}=\dfrac{0.1}{0.25}\cdot100\%=40\%\%0-\)

a, PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,5\left(mol\right)\)

\(\Rightarrow m_{Zn}=0,5.65=32,5\left(g\right)\)

\(\Rightarrow m_{CuO}=72,5-32,5=40\left(g\right)\)

c, Ta có: \(n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{Zn}+n_{CuO}=1\left(mol\right)\)

\(\Rightarrow b=C_{M_{H_2SO_4}}=\dfrac{1}{2,5}=0,4M\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnSO_4}=n_{Zn}=0,5\left(mol\right)\\n_{CuSO_4}=n_{CuO}=0,5\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnSO_4}}=\dfrac{0,5}{2,5}=0,2M\\C_{M_{CuSO_4}}=\dfrac{0,5}{2,5}=0,2M\end{matrix}\right.\)

Bạn tham khảo nhé!

a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\left(I\right)\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\left(II\right)\)

b, Theo PTHH(1) : \(n_{Zn}=n_{H_2}=0,5\left(mol\right)\)

\(\Rightarrow m_{Zn}=32,5\left(g\right)\)

\(\Rightarrow m_{CuO}=m_{hh}-m_{Zn}=40\left(g\right)\)

\(\Rightarrow n_{CuO}=\dfrac{m}{M}=0,5\left(mol\right)\)

c, Theo PTHH (1) và (2) : \(n_{H2SO4}=n_{CuO}+n_{Zn}=1\left(mol\right)\)

\(\Rightarrow C_{MH2SO4}=b=\dfrac{n}{V}=\dfrac{1}{2,5}=0,4M\)

d, ( Chắc là thể tích coi như không đổi )

Thấy sau phản ứng thu được A gồm \(0,5molZnSO_4,0,5molCuSO_4\)

\(\Rightarrow C_{MCuSO4}=C_{MZnSO4}=\dfrac{n}{V}=\dfrac{0,5}{2,5}=0,2M\)

Vậy ...

Ta có: \(n_{N_2O}+n_{NO_2}+n_{N_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\left(1\right)\)

\(n_{HNO_3}=1,85.2=3,7\left(mol\right)\)

⇒ 10n_N2O + 2n_NO2 + 12n_N2 = 3,7 (2)

\(n_{Mg}=\dfrac{16,8}{24}=0,7\left(mol\right)\)

\(n_{Fe}=\dfrac{28}{56}=0,5\left(mol\right)\)

BT e, có: 8n_N2O + n_NO2 + 10n_N2 = 2n_Mg + 3n_Fe = 2,9 (3)

Từ (1), (2) và (3) \(\Rightarrow\left\{{}\begin{matrix}n_{N_2O}=0,15\left(mol\right)\\n_{NO_2}=0,2\left(mol\right)\\n_{N_2}=0,15\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\%V_{N_2}=\dfrac{0,15}{0,5}.100\%=30\%\)

m _muối = m_Mg + m_Fe + 62.(8n_N2O + n_NO2 + 10n_N2) = 224,6 (g)

Đề câu 2 sao khỏi làm đi